CYTOP

CYTOP™ Technical Information

CYTOP™ is innovative in its field, showcasing the same excellent chemical, thermal, electrical, and surface properties as conventional fluoropolymers. In addition, its noticeable characteristics include high optical transparency and good solubility in specific fluorinated solvent, due to amorphous morphology.

CYTOP™ is the registered trademark of Japan.

Characteristics
High Transmittance
DUV 200nm – NIR 2.0 micron meter > 95%
Low Refractive Index
Minimal Colour Observation
nD:1.34, Abbe’s #: 90
Electrical Properties
Dielectric Constant:2.1,
Volume Resistivity>1017 ohm meter
Thin Film Coating
Soluble in perfluoro solvent:
Film Thickness beyond 0.1micron meter
Fluoropolymer Category
Fluoropolymer Perfluoropolymer
Crystalline ETFE
PVDF
PVF
ECTFE
PTFE
PFA
FEP
Amorphous Resins Lumiflon (1) Cytop (1)
Rubber Aflas (1)
Vitom (2)
Fluorel (3)
Kalrez (2)
Registered Trademarks: (1) Asahi Glass, (2) DuPont, (3) 3M

Applications 

  • Electronics Sector (inter-level dielectric layer for semiconductors)
  • Pellicle (Photo mask Cover)
  • Optical Sector (optical film, anti-reflection coating)
  • Graded-Index Optical fibre (Lucina™ for gigabit communications)
  • Other water & oil repellent/transparent anti-corrosion applications

(1) Optical Properties

CYTOP PTFE PFA PMMA Remarks
Refractive Index 1.34 1.35 1.35 1.49 Abbe’s Refractometer
Transmittance (%) 9.5 Opaque Opaque 93 Visible Region,200 micron meter
Abbe’s Number 90 55 Abbe’s Refractometor

UV-Vis. Transmittance

UV-Vis. Transmittance

(2) Physical Properties

CYTOP PTFE PFA PMMA Remarks
Glass Transition
Temperature (°C)
108 (130) (75) 105-120 DSC
Melting Point (°C) not observed 327 310 iso 160
syn 200
DSC
Density (g/cm3) 2.03 2.14-2.20 2.12-2.17 1.19-1.20 25°C
Contact Angle of
Water (degree)
110 114 115 80 25°C
Critical Surface
Tension (dyn/cm)
19 18 18 39 25°C
Water Absorptivity (%) <0.01 <0.01 <0.01 0.3 60°C
In water
Durometer Hardness HDD78 HDD55 HDD58-60 HDD92 ASTM D2240
Linear Expansion
Coefficient (cm/cm/°C)
7.4*10-5 1.0*10-4 1.3*10-4 8.0*10-5 TMA (40-100°C)

Contents

Gas Permeation Comparison of Oxygen
Gas Permeability (cm3cm/cm2s Pa) Product Oxygen Permeation (cm3 cm/cm2s Pa)
He 8.9*10-12 CYTOP 4.2*10-13
O2 4.2*10-13 PTFE 3.2*10-13
N2 1.0*10-13 PE 2.2*10-13
Saran 4.0*10-16
Moisture Permeation
Product Permeability (cm3 cm/cm2s Pa)
CYTOP 1.1*10-12
PI 4.3*10-11
Silicon Rubber 3.2*10-9
HDPE 9.0*10-13
Saran 7.0*10-13

(3) Chemical Resistance

Chemicals Weight Change(%) Appearance Remarks
Acids
12N HCl
99% H2SO4
50% HF

0.0
0.0
0.0

No change
No change
No change

60°C *1 week
60°C *1 week
R.T.*1 week
Alkalis
10% NaOH
44% NaOH

0.0
0.0

No change
No change

60°C *1 week
60°C *1 week
Organic Solvents
Hexane
Benzene
Acetone
Methylethylketone
Trichloro Ethylene
Carbon Tetrachloride

0.0
0.0
0.0
0.0
0.0
0.0

No Change
No Change
No Change
No Change
No Change
No Change

R.T.*1 week
R.T.*1 week
R.T.*1 week
R.T.*1 week
R.T.*1 week
R.T.*1 week

Before using CYTOP™, AGC Chemicals Europe urges the careful reading of the appropriate Material Safety Data Sheet (MSDS). Technical information brochures are available for selected products. Please note that the brochure and MSDS are based on the latest information and data available—additional corrections may be made from time to time without notice when new data becomes available and/or regulations are changed. Please contact AGC Chemicals Europe or the selling agency directly for any questions.

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